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mcm-41 nanoparticles mcm41mesoporous silica alumina as a catalyst h-mcm-41MWW structure

Brief Introduction

Mobil Composition of Matter No. 41 (MCM-41) is a mesoporous material developed by the Mobil Oil Corporation. MCM-41 is part of a family of silicate and alumosilicate solids that are well-suited for use as catalysts and catalytic supports.

The reaction is summarized as below

Typical physical and chemical property

Applications:MCM-41 was widely used in several fields, including catalysis and catalytic support, due to its remarkable textural properties. This material cannot be used directly in catalysis due to its inner surface containing only silanol groups. Therefore, several attempts were proposed in order to obtain an effective catalyst. The immobilization of metal complexes on the surface of mesoporous silica is one of the most popular methods. The metal complexes immobilized on the mesoporous silica MCM-41 exhibit significant catalytic activities due to the increased dispersion of the active sites and the faster diffusion of large organic molecules. The strong interactions between the metal and the ligand generate significant stability for this kind of catalyst, which allows them to be reused in several cycles without losing their efficiency. This review mainly discusses the immobilization strategies of different metal complexes supported on the mesoporous silica MCM-41. A recent study was presented and well detailed based on the different preparation methods, catalytic applications and the stability of metal complexes supported on mesoporous silica MCM-41.


Specification

Name
MCM-41   Molecular Sieve
Other name
MCM-41   Zeolite
Brand
DZC
Appearance
White powder
SiO2/Al2O3 mole ratio
25,40,60,80,120,200,300,600,>1000
Relative crystallinity(%)
≥90
Total surface area (m2/g)
≥400
Loss of ignition (wt%)
≦5
Particle size D50,Vol(um)
≦10
Na2O (wt%)
≦0.05